Current Approaches for the Process Mineralogy of Platinum-Group Element Ores and Tailings

Characterisation of platinum-group element (PGE) deposits and their process products has many challenges for the process or applied mineralogist. It is now well established that the PGE distribution for such samples is variably divided between submicroscopic concentrations of PGE in sulfides, tellurides and related minerals occurring as discrete platinum-group minerals (PGM), of which there are a large number of species, many with partial replacement between the PGE and between anions. Each PGE deposit type requires a targeted approach but fundamentally, there are two general methodologies in vogue. One way is to make a large number of polished or polished thin sections for detailed scanning electron microscopy (SEM)/optical examination to determine the PGM distribution and their associations and grain sizes. The other is to make concentrates of representative crushed or processed samples, thus having fewer subsamples to examine. Our method of choice is to use hydroseparation (HS) for concentration. HS provides representative concentrates of sizes down to ~10 ¦m, not possible by other techniques. Various microbeam methods have been used for analysis of trace quantities of PGE (EPMA, micro-PIXE, SIMS and LAM-ICPMS). We prefer LAM-ICPMS (laser ablation microprobe û inductively coupled mass spectrometry) because of the relatively large analytical volume sampled, the ability to measure all the PGE, monitor up to 20 elements, together with detection levels in the tens to a few hundreds of ppb. We provide typical results derived in studies of stratiform PGE ores and tailings, and a massive Ni-Cu sulfide ore.