Control Of Industrial Sulfur Dioxide Emissions Using Carbonate Rock Materials

Electric-power-generating plants fired by fossil fuels are faced with increasingly stringent requirements for control of sulfur emissions. Several approaches for limiting these emissions, or for operating such facilities in an environmentally acceptable manner, are being pursued. Some of the approaches are based on the use of naturally occurring carbonate rocks or of materials derived from them. This paper discusses primarily the carbonate-rock-based processes being developed for control of sulfur dioxide emissions from fossil-fueled electric-power-generating plants. It includes a discussion of the role of carbonate rock materials in removal of sulfur dioxide from stack gases after combustion, capture of gaseous SO2 during the combustion process, and removal of sulfur from fuel prior to complete combustion. Materials derived from carbon- ate rocks are generally used in processes which convert the sulfur to a throwaway product, but there are also proposed processes in which the sulfur is converted to a useful product and the absorbent is regenerated for reuse.