Commercial Chelating Extractants as Collectors: Flotation of Copper Minerals Using "LIX" Reagents

This study initiated to explore the potential of commercial chelating extractant for beneficiation of minerals revealed "LIX "65N to be an excellent collector for cuprite and chrysocolla. The collector action of the LIX is proposed to result from its chelation with copper species on the surface of the minerals. Thus, the syn-isomer of LIX65N, which is unable to form a chelate with copper ions, failed also to act as a collector. The proposed mechanism takes into account partitioning of LIX between the mineral surface (to form a surface chelate) and the copper chelate dispersed in the bulk aqueous phase (either due to formation of the chelate with dissolved copper, or due to detachment of chelate formed at surface). The efficiency of the collection is dependent upon this partitioning since the bulk chelate is found unable to collect. The marked decrease in flotation obtained when copper was added to the system supports this mechanism. The dependence of flotation of chrysocolla and cuprite on pH and reagentizing time is discussed on the basis of the proposed mechanism. Batch laboratory flotation tests using synthetic mixtures of oxide, sulfide and mixed oxide-sulfide copper minerals with quartz demonstrated the ability of LIX to separate the copper minerals from quartz.