Coastal deposits of heavy mineral sands; Global significance and US resources

"Ancient and modern coastal deposits of heavy mineral sands (HMS) are the principal source of several heavy industrial minerals, with mining and processing operations on every continent except Antarctica. For example, HMS deposits are the main source of titanium feedstock for the titanium dioxide (TiO2) pigments industry, obtained from the minerals ilmenite (Fe2+TiO3), rutile (TiO2) and leucoxene (an alteration product of ilmenite). HMS deposits are also the principal source of zircon (ZrSiO4), from which zirconium dioxide (ZrO2) is obtained for uses mostly in refractory products. Sometimes monazite [(Ce,La,Nd,Th) PO4] is recovered as a byproduct mineral, sought for its rare earth elements, and thorium (Ault and others, 2016; Sengupta and Van Gosen, 2016; Van Gosen and Tulsidas, 2016).HMS are sediments containing dense (heavy) minerals that accumulate with sand, silt and clay in coastal environments, locally forming economic concentrations of the heavy minerals (Fig. 1). Economic (mined) HMS deposits include Holocene sediments on modern coasts, such as examples in India and Brazil, as well as coastal deposits formed by transgressions and regressions of the seas during intervals in the Quaternary, Tertiary and Cretaceous, such as in Australia and the southeastern United States. Economic deposits typically contain heavy-mineral concentrations of at least two percent. Individual heavy minerals are commonly defined as minerals with a specific gravity greater than approximately 2.9 g/cm3. These minerals are generally resistant to chemical weathering and physical degradation and thus survive well in fluvial and coastal environments. Heavy minerals in coastal HMS deposits may include, in order of general abundance, ilmenite, leucoxene, rutile, magnetite, zircon, staurolite, kyanite, sillimanite, tourmaline, garnet, epidote, hornblende, spinel, iron oxides, sulfides, anatase, monazite, cassiterite and xenotime. Of these, ilmenite, leucoxene, rutile and zircon are the primary economic minerals. Garnet, monazite, cassiterite and xenotime are occasionally recovered as byproducts. The heavy minerals as a suite typically make up no more than 15 weight percent of a deposit and usually much less. Quartz and clay minerals form the bulk of the sediment. The geology of HMS deposits and examples of significant districts are summarized in Van Gosen and others (2014) and Hou and Keeling (2016)."