CO2, Alkalies and REE Systematics in Hydrothermally Altered Gabbro Hosting the Cordova Gold-bearing Veins, Ontario

"The earliest gold-mining operations in Ontario included the Cordova, Deloro, and Sophia mines north of Lake Ontario (see for example, Miller and Knight, 1914). The Cordova deposit, worked intermittently between 1891 and 1940, is reported to have yielded 22 774 oz of gold from 127 670 tons of ore averaging 0.19 oz/ton Au (Gordon et al., 1979). The property remained inactive for many years. In 1988, Gunnar Gold Inc. and Mill City Gold Inc. conducted a drilling program along the main Cordova vein. The present study is based on core from three drill holes through the Cordova gabbro (Fig. 1) and the carbonate alteration zones enveloping the quartz-carbonate veins. The relatively narrow width of the alteration zone and the availability of continuous sections of core provided an opportunity to conduct a compact mineralogical-chemical study of carbonate alteration and its effect on the redistribution of rare earth elements (REEs). Although the Cordova deposit is not of great economic importance, this study has revealed a number of interesting features which are interpreted as resulting from processes that may be applicable to gold-bearing quartz vein deposits elsewhere.The Cordova gabbro is layered in places, varying from fine-to coarse-grained and in color from light gray (feldspathic) to dark gray-green (amphibolitic). However, layering within the section of the gabbro considered here and which hosts the Cordova gold deposit is mainly textural rather than compositional. Samples of unaltered gabbro selected for analyses were medium- to coarse-grained; amphibolitic and anorthositic phases were avoided as being less representative of the general chemical composition of the gabbro.The Cordova intrusion has undergone regional metamorphism and consists dominantly of actinolite and saussuritized plagioclase with smaller amounts of granular clinozoisite and flaky chlorite; minor quartz, ilmenite, titanite, apatite, and calcite are typically present. Some actinolite grains have irregular rims of pleochroic green hornblende that is optically continuous with the actinolite. Both chlorite and clinozoisite occur in two modes. Chlorite occurs as an alteration product of actinolite and as separate grains in the groundmass. Clinozoisite and albite occur together as regional metamorphic alteration products of original plagioclase crystals and as discrete grains in the matrix.The main gold-bearing quartz-carbonate occurrence occupies an easterly trending, steeply southward-dipping carbonatized shear zone up to 15 m wide and 700 m long. The gold occurs principally in irregular lenses and veins of quartz-carbonate up to a foot thick occupying the lower part of the schistose shear zone within the gabbro. This zone consists of chlorite, biotite, and carbonate and is flanked on both sides by chlorite-carbonate schist lacking biotite. The chlorite-carbonate schist in turn grades into regionally metamorphosed actinolite-bearing undeformed gabbro.The dominant sulfide within the quartz-carbonate lenses and in the surrounding schist is pyrite which occurs mainly as small cubes (1 mm to 2 mm) generally making up less than 10% of the rock. Rare blebs of chalcopyrite are present. Magnetite is common throughout the schist."