Characterization Of The Resin Fraction From Various Low-Temperature Tar Pitches

RESINS from a bituminous pitch, a bituminous coal, a lignite tar, a subbituminous pitch, and an electrode binder pitch wore investigated by the Bureau of Mines. The compositions of these resins were determined by four independent methods of structural detemination: (1) Molecular formula and ring analysis, including ring (2) infrared and ultraviolet spectra; (3) combined pyrolysis/gas chromatography, and (4) catalytic dehyrogenation followed by spectra and pyrolysis. The resin structure was correlated with coal structure, and it was concluded that pitch resins probably consist of essentially unaltered coal molecules carried over with the tar vapors in low-temperature carbonization.