Cadmium Removal By Biosortion-Bioflotation Process Using Rhodococcus Opacus As Biosorbent

The elimination of metal ions from aqueous solutions by biosorption plays an important role in water pollution control. Heavy metals are hazardous to the aquatic ecosystem and pose possible human health risk. Beside the toxic and harmful effects to organisms living in water heavy metals also accumulate throughout the food chain and may affect human beings. Conventional methods for removing metals from aqueous solutions before they are disposed of include chemical precipitation and sludge separation, chemical oxidation or reduction, ion exchange, reverse osmosis, electrochemical treatment, and evaporation. Alternative processing methods are being considered more seriously. Sorption and/or complexation of dissolved metals species based on the chemical activity of biomass, known as biosorption, is the base of the new technology for metal removal and recovery. Different types of biomass (dead and alive) have been investigated for biosorption of heavy metals ions. In the present work, the cadmium biosorption capacity and bioflotation of Rhodococcus opacus were studied. The adsorption capacity of biomass was investigated by batch experiments, the influences of some variables like pH and ion concentration were evaluated and the experimental data obtained for each metal were evaluated and fitted using adsorption and kinetic models. The bioflotation process showed that R. opacus has excellent features as collector and foaming agent after metal biosorption. Around 90% of cadmium uptake by the biomass was achieved by bioflotation.