Atmospheric Carbon Elution Without the Use of Cyanide at Barneys Canyon Mine (fa87e69c-1e2d-4d89-9be4-be83056d26b0)

In recent years, much work has been done to explain the nature of the gold-carbon adsorption mechanism. The benefits of a sound theoretical basis has the obvious application to gold adsorption and elution industrial processes. Unfortunately, the lack of a clear agreement on the mechanism has provided no clear direction towards process innovation and optimization. Jones' (1989) work has gone a long way towards clarifying the specie of gold adsorbed (and thus the chemistry required to remove it). Since the development of hot caustic and cyanide elution, the kinetics have been accelerated by the application of pressure to increase elution temperatures beyond the boiling point at atmospheric pressure. However, the traditional reagent content of 15 g/L NaOH and 5-10g/L NaCN has remained largely unchanged. This is in spite of work that has shown that the presence of cyanide is not required for the elution process to take place (Adams, 1986; Adams; 1989; Jones, 1989). Adams (1989) has also compared NaOH elution rates with and without cyanide. He found improvement with the use of cyanide and a synergistic effect with the use of both. Others have found no difference in overall extraction (Jones, 1989