Assessment of the Durability of Cementitious Barrier Materials

"This paper draws together some themes on the durability of barrier systems, and particularly cementitious systems. For contaminated land and water retaining structures, durability can be poorly addressed at all stages of a project, from specification, to barrier material selection, barrier design including toe-in and through to performance assessment in operation. Permeability (hydraulic conductivity) is a dynamic property which will vary over time as reaction processes propagate through a barrier. However, laboratory testing, when undertaken, tends to be focused on short term tests with aggressive chemicals so that the effects of longer-term processes such as carbonation and leaching by permeating water are missed. For water retaining structures, carbonation and leaching actually may be the most significant processes affecting barrier performance as the groundwater adjacent to many water bodies can be otherwise rather benign (as regards bentonite and cementitious systems). These and other reaction processes have been modelled in the arena of nuclear waste repositories and procedures are well recognised. However, such procedures have yet to be widely adopted for the assessment of other barrier systems.INTRODUCTIONOver the last few decades there has been an enormous amount of laboratory research on the durability of barrier materials or more specifically papers reporting the results of permeability tests. Unfortunately there is a much smaller literature on scaling test results to barrier dimensions in the field or to required design lives. Although in the geotechnical industry durability research has been largely laboratory based, in the nuclear industry where relevant timescales are multi-millennia rather than decades, research has been heavily underpinned by geochemical modelling. A significant purpose of this paper is to examine the tools that may be used to analyse the results of tests on barrier materials used in geotechnical engineering, for example, for water retaining structures and contaminated land and draw the attention of the construction industry to the potential of the modelling procedures developed for nuclear repository assessments. Modelling can help to identify underlying processes and so augment information from laboratory testing focused on changes of physical properties such as permeability and strength."