Arsenic Mineralogy in a Simulated Uranium Mill Tailings Neutralization Process

The uranium milling process at the Key Lake Operation of Cameco in Northern Saskatchewan, Canada results in the leaching of untargeted metal(loid)s such as arsenic, iron and nickel that are found at high concentrations in the ores. To mitigate the environmental impact of the leached As, Fe and Ni in the mill waste solution (raffinate), the pre-discharge mine tailings (rafffinate and residue) are neutralized with slaked lime, resulting in the formation of secondary As-, Fe- and Ni-bearing mineral phases which serve to control their concentrations to very low levels in the tailings porewater. As part of an ongoing investigation into the long-term evolution (10,000 year) of arsenic mineralogy in the Deilmann Tailings Management Facility (DTMF) at Cameco?s Key Lake Operation, it has become necessary to characterize secondary As-bearing mineral phases during the neutralization process prior to the discharge of the tailings and compare these to in situ As-bearing mineral phases in the tailings facility. This is primarily to determine if changes have occurred over time to As-bearing mineral phases in the tailings facility as well as to investigate whether alternate neutralization techniques may have a beneficial effect on the stability of mineral phases formed. Thus a bench-scale model was developed and preliminary testing conducted to simulate the mill neutralization process (i.e. neutralization of synthetic raffinate solutions with incremental amount of slaked lime to terminal pH values). The resulting ?tailings? (precipitates and supernatant) were then separated and analyzed. XRD analysis of the precipitates shows that the Fe occurred mostly as ferrihydrite. This was complimented with results from Raman spectroscopy which further indicated that the As appeared adsorbed onto the ferrihydrite. Results of geochemical modeling of the bench-scale test compared well with supernatant profiles from ICP-MS analysis.