Application Of Competitive Complexation / Solvation Theory In Metals Solvent Extraction: New Opportunities In Process Development.

Competitive complexation/solvation theory of solvent extraction constitutes a general framework for interpretation and quantification of ion-molecular interaction data in extraction systems. Depending on extracting metal -- solvent affinity constant and metal concentration ratios, four possible stages of extraction behavior and interacting mechanisms, are considered. Affinity constant ratios are easily acceptable through the independent measurements of three-component systems. Once determined and tabulated, the affinity constant ratio data may be used in any system of interest. Mathematical descriptions of the results are introduced for different interactions. Active solvent (including water) concentrations in the organic phase and temperature are included to the quantitative consideration. The theory allows direct comparison of the complexing/solvating power (competition order) of various extractants, active solvents and diluents. As a result, predictions for the extraction effectiveness and selectivity are possible. Some metal extraction systems are analyzed on the base of the theory. Analysis gives a key for preliminary quantitative prediction of suitable extraction systems.