Analysis Of Roman Wall Paintings From Ancient Corinth/Greece

Eighty samples from Roman wall paintings from ancient Corinth were studied by means of optical and scanning electron microscopy coupled to an energy dispersive analyzer, X-ray diffraction and image analysis techniques. The goals of the study were the identification of the exact nature of the pigments and the technical features of paint application (binding medium, adherence to plaster, thickness of the pigment layer), which would provide evidence about the painting technique (fresco or secco). The main plaster is calcitic with secondary calcite as a cement binder to the primary calcite grains. All pigments, except Egyptian Blue, were naturally occurring ochres or pigment minerals, such as limonite, goethite, hematite for yellow, brown and red hues, cinnabar for red hues and celadonite for green color. The presence of specific elements such as Ni and Cr or minerals such as olivine, in the yellow, brown and red pigments, gave an indication about the provenance of the original pigments, which seems to be from Cyprus. The black color was represented using charcoal. It seems, finally, that for the pigment application the fresco technique was used, while secco is also apparent.