An Integrated Process Including Rb Leaching from Rubidium‑Bearing Polymetallic Ore and Calcium Removing from Leachate - Mining, Metallurgy & Exploration (2023)

In the traditional chlorination roasting-water leaching-solvent extraction process for the extraction of rubidium-bearing ore, Rb leaching from the ore and calcium removing from the leachate are conducted separately, and this results in the complicated process and high energy consumption. In order to integrate the Rb leaching and calcium removing processes, Rb-bearing polymetallic ore was firstly treated by chlorination roasting, it was then leached in a micro-reactor with raffinate, and the calcium ions in the leachate were removed in the reactor as carbonate precipitates by passing CO2 at certain pressure into the reactor. The effects of raffinate alkalinity, CO2 pressure, and CO2 reaction time on Rb leaching rate and calcium removing rate were investigated. The experimental results show that when Rb-bearing polymetallic ore was leached for 90 min by stirring with raffinate with 1.125-mol/L alkalinity, and the pulp was made to react with CO2 at 0.8 MPa for 15 min, the Rb leaching rate and calcium removing rate amounted to 92% and 98.2%, respectively. This integrated process including Rb leaching from Rb-bearing polymetallic ore and calcium removing from leachate could simplify the process for the extraction of Rb-bearing ore and increase its economic benefits.