An Efficient Recycling Process of Rare Earth Metals Using Ionic Liquids

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."