Alternative To Lime As A Rheology Modifier In The Transport Of Iron Ore Slurry By The Samarco Pipeline

Lime has been added to the iron ore slurry transported by the Samarco pipeline since its operation start-up in 1977.Initially, internal corrosion was the main concern therefore the reagent was used only for pH correction. Over the last ten years, though, transport of more complex slurries demanded a significantly higher dosage of lime to guarantee adequate rheology control. Several other reagents have been tested for the same purpose yet none has proven to be as effective regarding technical performance, environmental impact and cost. However, an alternative was sought so that the slurry rheology could still be controlled in case lime addition became impracticable. The objective of this paper is to present a technical solution for this matter, which takes into account environmental aspects. It consists of adding soda for pH correction and an organic coagulant as a rheology modifier. The latter is a quaternary ammonium salt which affected the slurry transport properties in the same manner as lime when tested in a laboratory. It showed no plug formation and allowed solid particles to settle, forming a loose sediment after rest. These results indicate a low probability of plug occurrence in the pipeline and the formation of a readily reslurryable sediment upon shutdown of the pumping system. Industrial tests should be performed in order to validate the laboratory results.