Advanced techniques using microscopy to quickly assess emulsion quality and stability.

Emulsions have been developed for over forty years to become the most common water-resistant explosives used in the mining industry. An emulsion is a common commodity, with many examples in our day to day lives of one immiscible liquid dispersed in another. They have varying degrees of stability from a few seconds to years. What makes their application in explosives unique is twofold. They contain a high concentration of salts in the dispersed phase and also have a far larger volume of dispersed phase than continuous phase. The continuous phase contains at least 75% by weight of an oxidizer such as ammonium nitrate dissolved in water. The crystallization point of these solutions is often >60oC which means that the formation of the emulsion has to occur at an elevated temperature. Once the emulsion is cooled, its structure helps to prevent the formation of crystals in an otherwise unstable system. At room temperature there is a considerable potential for the small oxidizer droplets to crystallize which is countered by the strength of the oil layer and also the size of the emulsion droplet. If the emulsion droplet is too large then crystals can form which may lead to rapid deterioration of the emulsion and overall crystallization, accompanied by a temperature rise as the heat of crystallization is released from the emulsion. The size of the emulsion droplet is critical in preventing crystal growth and subsequent droplet coalescence and emulsion break down. One method of examining emulsions and understanding their structure is to use optical microscopy to measure droplet size and also emulsion deterioration from shearing, temperature cycling and when contaminants are introduced, such as detergents, different oil types, coating agents and dust particles. This paper reports on advanced techniques to quickly assess emulsion quality and stability