Adsorption-Coagulation Mechanism of Composites in Treating Acid Mine Drainage

"In order to study the removal efficiency of Cu2+ from acid mine drainage by prepared bentonite-steel slag composite particles, adsorption experiment was carried out. The composite particles were characterized by X-ray Diffraction analysis technique (XRD), Scanning Electron Microscopy (SEM) and Fourier Transform Infrared spectrometer (FTIR). The results show that: the composite particles can release alkali to neutralize the acid of acid mine drainage; the adsorption and chemical precipitation of Cu2+ occurred in the whole reaction process; the removal amount of composite particles on Cu2+ was 9.88 mg/g when the reaction reached equilibrium; the FTIR spectra revealed the existence of surface complexation; the SEM micrographs suggested that the composite particles would continue to adsorb and coagulate Cu2+ after the composite particles surface adsorbing Cu2+ and forming precipitate, namely, there was synergistic reaction of adsorption and coagulation; the XRD patterns further showed the existence of cation exchange and revealed that the states of Cu2+ in the surface of the composite particles was Cu-Si-O mineral phase and CuO(Cu(OH)2) polymerization precipitation. The bentonite-steel slag composite particles which can play a role of adsorption-coagulation synergism are excellent multifunctional green environmental mineral materials to treat acid mine drainage containing heavy metal ions.Introduction It is reported (Zuo and He 2013) that with the rapid development of industry, the world demand for mineral resources is increasing, while the problem of mine environmental pollution is becoming more and more serious due to the large amount of mining. The pollution of mine wastewater has become a global problem, in which acid mine drainage (AMD) is one of the most serious waste water. It is also reported (Cong and Zhao 2003) that acid mine drainage containing high concentrations of heavy metals and having low pH value, causing serious negative influence to the mining production and ecological environment. Acid mine drainage is one of the most serious environmental pollution to the mining industry. In recent years, it has been widely concerned by scholars at home and abroad."