Activated Alumina For The Removal Of Selenium From Heap Leach Detoxification Solutions

The use of activated alumina for the removal of selenium from heap leach detoxification solutions was studied at a laboratory scale. Three different aluminas were studied, one unmodified and two chemically modified to function better in a basic pH range. The best performer, Discovery Chemicals DD-6, readily accumulated selenium oxyanions. Furthermore, it could be stripped of selenium and several metals by a mild caustic solution (pH 11.5 – 12.0) and regenerated for further use. Tests using - 600 µm, + 300 µm (28 x 48 mesh) material indicated that 96 % could be removed from solution and using – 1.18mm, + 600 µm (14 x 28 mesh) material 91 % could be removed. However, soluble silica can accumulate on the activated alumina and subsequently interfere with its regeneration and should be removed from the detox solution prior to use of the adsorbent.