A Simple XRF Fusion Method for Mineral Exploration Samples: Determination of Nickel and Gallium

A new low-dilution fusion method which has been successfully used for accurate determination of the major oxide components of silicate rocks, is applicable to rapid, accurate determination of trace or minor eiements in mineral exploration samples. Limit of detection is in many cases less than 5 ppm. Either rapid, approximate measurement and calculation methods (suitable for geochemical exploration), or more accurate methods (applicable to orebody evaluation studies) may be used.Rapid methods are described for nickel in rocks and sulphides containing 10 ppm to >2 per cent Ni, and for gallium. The rarely-determined element gallium is an example of a constituent which may be easily investigatedby XRF using the LiB02 fusion disc, which is a permanent, easily-stored analytical sample available for later rapid or accurate analyses. The method is applicable to over 30 elements at levels encountered in mineral exploration.