A Simple Method of Thermal Analysis Permitting Quantitative Measurements of Specific and Latent Heats

THE method of thermal analysis, so important in the development of metallographic science, has of recent years been falling into disuse owing to the development of other physical methods which give results easier of interpretation and which can be used for the study of either equilibrium or transitional conditions because they do not require a continuously changing temperature. Nevertheless thermal analysis remains useful in the study of reactions that take place rapidly, and the simplicity of the experimental technique and the general availability of the apparatus involved are points in its favor. Theoretically, thermal analysis is capable of giving specific and latent heat measurements and therefore should permit the study of reactions on a more fundamental basis than any other method. It is, however, difficult or impossible to obtain quantitative heat measurements from cooling curves obtained in the usual way. Even if the furnace containing the sample is cooled or heated at a linear rate, or if a gradient furnace is employed to maintain a constant rate over a large range of tempera-ture, the heat flow from or to the specimen depends on its previous his-tory, for the difference of temperature between the specimen and its surroundings varies. The emissivity of the specimen surface, moreover, is unlikely to be constant. The able mathematical analysis by Russell,1 although it prevents misinterpretation of data, has an effect rather the reverse of that intended, and leaves the reader doubtful of the possibility of ever obtaining quantitative results from thermal curves. Nothing can be done to apply thermal analysis to the study of equilib-rium conditions of reactions that are not completed at rates of tempera-ture change below about 1° C. per minute, and this unfortunately excludes most solid transformations in alloys. ? For the determination of liquidus