A Process For Enhanced Removal Of Iron From Bauxite And Clay

Processing bauxite and clay ores to reduce Iron content to levels low enough for the ores to be suitable raw materials for such products as refractories and abrasives has long been regarded as a diffi9ult problem. Standard magnetic separation processing of the untreated ore has been attempted by previous investigators with only limited success due to the finely divided state and weak magnetic susceptibility of the iron minerals (hematite, geothite, etc.) present in these ores. The new process described in this paper consists of calcining the finely crushed ore at 500 to 800 C and then reducing (with hydrogen, carbon monoxide, etc.) the iron oxides present to magnetite or elemental Iron. The magnetic susceptibility of iron in these forms is enhanced 40-to 100-fold over that of hematitie and is readily removed by simple magnetic separation. Starting with a 2.7% Fe20s Alabama bauxite ore, a 1.5% Fe20s product was produced in one pass through a Davis tube magnetic separator with 95 + % recovery of the iron-free bauxite fraction and a 20% Fe20a magnetic product. These findings suggest that with the addition of light calcination, reduction and magnetic separation steps to the conventional refractory grain production process, the large U.S. reserves of high-iron bauxites could be used.