A Historical View of Dewatering of Phosphatic Clay Waste Using Polyethylene Oxide

The U.S. Bureau of Mines has thoroughly investigated the flocculation of phosphatic clay waste with polyethylene oxide (PEO). The studies included both theoretical and applied aspects of the flocculation sequence. The screen dewatering technique developed by the Bureau was field tested at four different Florida phosphate mines. The results of these field studies are presented. Also, to determine the mechanisms of the interaction of PEO with montmorillonite clays common to the phosphatic clay waste, a number of theoretical studies were conducted. An empirical equation was developed to describe the amount of PEO needed for flocculation. Infrared, ion exchange, and rheology techniques were used to study the interaction of PEO with Florida clays. The results of these studies are also presented.