A FUNDAMENTAL EVALUATION OF THE DuPONT ACTIVATOR TECHNOLOGY

The effect of an activator on gold dissolution in clear solution is examined using a rotating disk gold electrode. Steady state polarization curves for anodic dissolution of gold and cathodic reduction of oxygen indicate that the dissolution rate increases in the presence of the activator. The activator enhances gold disso­lution under standard cyanidation conditions; however, optimum activator concentration at the maximum dissolution rate is a function of the cyanide level. In the presence of an activator, the gold dissolution mechanism is controlled by surface kinetics and may be explained by a metal dissolution over-potential model. The dissolution rate with activator is higher than the dissolution rate at a higher cyanide concentration but without activator. The dissolution rate measurements indicate that 3 PPM of activator in a 500 PPM NaCN solution provides a higher dissolution rate than 1000 PPM NaCN alone. Activator technology may be a cost-effective means to reduce cyanide concentration.