A Dissolution Kinetic Model For Metals In Solutions

A kinetic model for the batch leaching of various metals using different lixiviants was developed. The overall material balances for the reactants and products at the solid/ liquid interface were formulated for various types of heterogeneous reactions at the interface. The solutions to these mass balances are identified analytically, as well as numerically. Applications of these numerical solutions to various leaching systems using rotating discs or powders are discussed. The metal-dissolution systems addressed include cobalt, nickel and copper in acid, cyanide and ammoniacal solutions.