A Cyanide Process Based On The Simultaneous Dissolution And Adsorption Of Gold

THE writer has carried on experimental work for several years with respect to the simultaneous dissolution of gold by cyanide and the adsorption of the dissolved gold on activated charcoal in ore pulps, followed by the recovery of the charcoal by flotation. The results of this experimental work have been sufficiently encouraging to suggest a new process based on the principle of simultaneous dissolution and adsorption of gold, applicable to certain ores and tailings that cannot be treated to advantage by countercurrent decantation or filtration. Applications for patents have been filed and The Dorr Company, Inc. has the exclusive right to license the use of the process. The purpose of this paper is to describe such a process, state its possible advantages and immediate field, and give some results obtained on a laboratory scale. EARLY EXPERIMENTAL WORK In the early stages of the experimental work attempts were made to precipitate soluble gold from cyanide solutions with zinc and aluminum in ore pulps followed by flotation of the precipitated gold, but since the results were not promising enough to continue with these precipitants attention was directed to carbon. The first experiments with carbon comprised the addition of cyanide and alkali to the ore pulp, the addition of carbon at or near the end of the dissolving period, and the recovery of the carbon by flotation. With this method of procedure the assumption was made that carbon functioned as a precipitant of gold from cyanide solutions and as such should be added as are other precipitants, including zinc and aluminum; namely, at the end of the dissolution period. The assumption was then made that carbon functioned as an adsorbent, and that if such assumption proved to be correct, it could be added with success to the ore pulp at the time of adding the cyanide. The first experiment along this line was successful in that the feasibility of the dissolution of gold by cyanide and the simultaneous extraction of the dissolved gold by carbon in ore pulps was demonstrated, at least with respect to such treatment on a laboratory scale.