A Comparison of Cyanide, Thiourea and Chlorine as Lixiviants for Gold

The dissolution of gold from various ore-bodies is discussed in terms of extraction rates and reagent consumptions during leaching. Gold dissolves slowly in cyanide but reagent consumptions are usually satisfactory. In almost all cases where excessive cyanide consumptions occur, similar high consumptions result with other lixiviants. Recovery of gold from cyanide solution is well established and comparatively simple technology.Gold dissolution in thiourea is faster than cyanide but significant consumptions of thiourea, due to both adsorption and oxidation, occur. Gold recovery from thiourea solutions is likely to be more difficult than from cyanide.Chlorination of gold is very fast in acidic conditions but excessive consumption of chlorine occurs for ores containing greater than 0.5% S. Reprecipitation of gold and handling of acidic chlorine solutions are both significant problems. The mechanism of gold reduction onto activated carbon creates difficulties in the carbon in pulp process for recovery of gold but means a simplification in the production of bullion from loaded carbon.