"Experimental Investigations of Phase Equilibria for Copper Smelting and Converting Silicate Slags in the ""CU2O""-FEOFE2O3- CAO-SIO2 System at Controlled Oxygen Partial Pressures"

"There is renewed interest in the improvement of existing copper smelting processes and the development of new technologies. It has become clear that further accurate information on slag properties, in particular, on phase equilibria are required in order to optimize these processes. It is in this context that improved experimental research methodologies have been developed specifically to provide information on phase equilibria at the oxygen partial pressures encountered in copper smelting practice. The methodology involves synthetic slag equilibration at controlled gas atmospheres, quenching and measurement of compositions of phases with an electron probe X-ray microanalyser (EPMA) with wavelength dispersive detectors (WDD). Application of modem analytical tools and careful design of experiments greatly improve accuracy of determination of phase equilibria in complex, multi-phase slag systems. New experimental data on phase equilibria for the copper smelting and converting silicate slags at controlled oxygen partial pressures in the temperature range between 1200°C and 1350°C in the ""Fe0""-Ca0-SiO2 system and in the ""Cu20""-""Fe0""-Ca0-Si02 system in equilibrium with metallic copper are reported, and differences between various data sources are analyzed."