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|The effects of nitrogen alloying on the corrosion properties of austenitic stainless steels were investigated by a combination of potentio-dynamic and surface analysis techniques. The results indicate that nitrogen undergoes the phenomenon of anodic segregation, affecting both general and localized corrosion resistance. Nitrogen alloying is found to be beneficial to general corrosion resistance in a de-aerated sulphuric acid solution, but to be detrimental in an aerated solution of sulphuric acid This phenomenon is explained in terms of an ammonium-ion polarization effect. Localized corrosion resistance is found to improve dramatically as a result of nitrogen alloying, the nitrogen improving the formation, maintenance, and stability of the passive film in environments that promote pitting various theories that have been proposed to account for these phenomena are discussed.|