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|The responses of calcite, feldspar and quartz minerals in a laboratory free-fall electrostatic separator after tribocharging with stainless steel, PVC and copper plates were investigated. The effects of H3BO3 and BaC12 chemical pretreatment on the electrical properties of the above minerals were examined. The changes in the electrical properties are discussed along with the determined charge, dielectric constant and electrical conductivity of the mineral samples. The electrical properties of the minerals and their responses to the electrical field during separation after tribocharging and chemical pretreatment are explored relative to the electrical behavior of the minerals.|