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|Cathodoluminescence microscopy (CLM) is uniquely applicable to the study of carbonatite-related fluorspar ore deposits. The mineralogy of the carbonatites, sodic and potassic fenites, marbles, quartzites and fluorite ores are readily determined and characterized. Calcite, dolomite, apatite and fluorite were deposited dominantly under high-temperature conditions, and they exhibit strong cathodoluminescence (CL). At the Okorusu, Namibia, carbonatite complex and fluorspar mines, three types of carbonatites have been recognized by field mapping and laboratory CLM. The main carbonatite intrusion is fine grained and consists mainly of calcite. A later phase of pegmatitic carbonatite consists of calcite, magnetite, Fe-rich pyroxene, apatite and pyrochlore. Pyroxene carbonatites were recognized mainly through their study by CLM.|