Ultra Fine Grinding of Yttria Stabilized Zirconia In Polyacrylic Acid Solutions
Organization: Society for Mining, Metallurgy & Exploration
Jan 1, 1992
Two different groups of mechanisms have been considered in the past to explain the effects of chemical additives on grinding. While one group of explanations is based upon alterations of surface and mechanical properties of the individual particles, the other group depends mainly on the arrangement of particles and their flow in suspensions. In this paper some of the past work on grinding aids is reviewed and attrition grinding of a commercially important ceramic material, zirconia (stabilized with yttria) with polyaaylic acid as grinding aid, is studied in order to determine the effect of the aid on the ground product itself. It was observed that even though polyaaylic acid did cause a drastic decrease in the viscosity of the pulp, it did not have any major effect on the grinding of zirconia at least up to 2000 ppm and only minor detrimental effect above it. Importantly, complexation by the polymer was found to cause extraction of yttrium into solution with possibly significant changes in the surface chemical composition of the product.