Kinetics and Mechanism of Zircon Chlorination

Glastonbury J R,
Organization: The Australasian Institute of Mining and Metallurgy
Pages: 9
Publication Date: Jan 1, 1973
The kinetics of the direct chlorination of, zircon in the presence of carbon was studied at temperatures between 9000C and 12000 C. From the experimental data it is prop- osed that the most likely mechanism for metal oxide (MeO2) chlorination is as follows: At I Surfaceon zMeO2+ZMeCl - MeOC12 (1) At Carbon MeOC12+C+Cl MeC14+CO (2) Surface It.is envisaged that this type of mechan- ism would occur for both the zirconium and, silicon. constituents of the ore. In the above mechanism; the surface re- actions appear to be fast and not rate controll- ing. In a carbon surface deficient bed the diff- usion of oxychloride intermediate through the boundary layer to the carbon surface becomes the rate controlling step. In a zircon surface deficient bed the diffusion of oxychloride away from the zircon surface controls the reaction. This postulated mechanism can be used to ex-, plain the observed experimental effects.
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